Vibrational structures of a few electronic bands of THIOFORMAMIDE (cas 115-08-2)

Add time:08/28/2019    Source:sciencedirect.com

Vibrational structures of four electronic bands of thioformamide were examined: Three were observed at 8.70, 9.30, and 15.52 eV in the photoelectron spectrum, and one was observed at 230 nm in the absorption spectrum. The four corresponding bands of thioformamide-d2 have also been examined. On the Condon approximation, and on the assumption that the vibrations are all harmonic, the amount of shift in the potential minimum along each normal coordinate, which is caused by each electronic transition (ionization or excitation), has been estimated.

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