Chapter 6 Stereocontrolled Synthesis of Mannans and rhamnan (cas 111018-90-7)s
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Add time:08/25/2019 Source:sciencedirect.com
The total synthesis of the α‐mannans, α‐rhamnans, β‐mannans, and β‐rhamnans is presented according to the overall strategy employed. The α‐mannans and α‐rhamnans are discussed in terms of the use of use or not of neighboring‐group participation to construct the 1,2‐trans‐axial glycosidic bond, whereas the β‐mannan and β‐rhamnan syntheses are classified as either direct or indirect, with the latter requiring additional steps post‐glycosylation to achieve the 1,2‐cis‐equatorial glycosidic linkage.
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