Rapid construction of polycyclic ring systems from aromatics: stereoselective synthesis of the carbon framework of vinigrol (cas 111025-83-3)

Add time:08/27/2019    Source:sciencedirect.com

The stereoselective syntheses of the tricyclic core structure of vinigrol and highly functionalized polycyclic molecules from 5-bromo-2-methoxyphenol in five synthetic steps are reported. Intramolecular and intermolecular Diels–Alder reactions and tandem oxy-Cope/ene reactions are the key steps in the synthesis.

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