Facile reductive rearrangement of dynemicin a to dynemicin H: the direct evidence for the p-phenylene diradical intermediate
-
Add time:08/26/2019 Source:sciencedirect.com
Dynemicin A rearranged smoothly to dynemicin H, on treatment with aqueous sodium hydrosulfite in dioxane. The same reaction in d8-dioxane gave dynemicin H deuterated specifically at 24- and 27-positions indicating the generation of biradical species at these positions.
We also recommend Trading Suppliers and Manufacturers of dynemicin S (cas 132645-97-7). Pls Click Website Link as below: cas 132645-97-7 suppliers
Prev:Research paperSynthesis of (+)-dynemicin A and analogs of wide structural variability: establishment of the absolute configuration of natural dynemicin A
Next:The Bergman reaction of dynemicin A – a quantum chemical investigation) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Bioreductive alkylation as a trigger for toxic effects of dynemicin08/30/2019
- Synthetic studies on antibiotic Dynemicin A. Synthesis of cyclic enediyne model compound of Dynemicin A08/29/2019
- Cross-coupling approach towards dynemicin analogs without the nitrogen08/28/2019
- The Bergman reaction of dynemicin A – a quantum chemical investigation08/27/2019
- Research paperSynthesis of (+)-dynemicin A and analogs of wide structural variability: establishment of the absolute configuration of natural dynemicin A08/25/2019
- Asymmetric synthesis of a new simplified dynemicin analogue equipped with a handle08/24/2019
- 1 - Dynemicin A08/23/2019
