Rearrangement and double fluorination in the deiodinative fluorination of Neopentyl iodide (cas 15501-33-4) with xenon difluoride

Add time:08/24/2019    Source:sciencedirect.com

Alkyl iodides give products from the neopentyl rearrangement on reaction with xenon difluoride. Neopentyl iodide (cas 15501-33-4) performs a double rearrangement and yields a gem-difluoro product, 2,2-difluoro-3-methylbutane. Studies of the mechanism show that an alkene intermediate is involved in the double rearrangement process. Alkenes can be substituted as substrates in reaction with xenon difluoride–iodine to give gem-difluoro products. 13C Labeling verifies the skeletal rearrangement process.

We also recommend Trading Suppliers and Manufacturers of Neopentyl iodide (cas 15501-33-4). Pls Click Website Link as below: cas 15501-33-4 suppliers

Prev:Studies into the carbon doping of GaAs, AlGaAs and AlAs grown by CBE using Neopentyl iodide (cas 15501-33-4)
Next:Neopentyl iodide (cas 15501-33-4) on Pt(111) I. Adsorption and thermal decomposition)