N-substituted-3(10H)-acridones as visible-light photosensitizers for organic photoredox catalysis

Add time:07/14/2019    Source:sciencedirect.com

N-Substituted-3(10H)-acridones have been established as visible-light organic photocatalyst. These photosensitizers are efficient for oxidative coupling reaction of N-aryl tetrahydroisoquinolines with various nucleophiles. Notably, N-methyl-3(10H)-acridone (Ia) is stable and can be effectively prepared. It is a water-soluble and atom-economic catalyst, and thus holds promise for green chemical applications. Mechanistic studies confirm a single electron transfer (SET)-induced radical process and a rate-limiting step. Analysis of the photocatalytic reactivity−structure relationship reveals that the acridones are robust and tunable photosensitizers for photoredox catalysis.

We also recommend Trading Suppliers and Manufacturers of 3-Chloro-9(10H)-acridinone (cas 6269-27-8). Pls Click Website Link as below: cas 6269-27-8 suppliers

Prev:Antiviral activity of 9(10H)-Acridanone extracted from marine Streptomyces fradiae strain VITMK2 in Litopenaeus vannamei infected with white spot syndrome virus
Next:An asymmetric synthesis of both enantiomers of 2,2,2-trifluoro-1-furan-2-yl-ethylamine and 3,3,3-trifluoroalanine from 2,2,2-trifluoro-1-furan-2-yl-ethanone)