A channel rotaxane coordination polymer (RCP) based on the assembly of p-sulfonatocalix[8]arene and 4,4′-bipyridine-N,N′-dioxide ligand
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Add time:08/30/2019 Source:sciencedirect.com
In this paper, we report the first rotaxane structure of p-sulfonatocalix[8]arene as part of a supramolecular 3D co-ordination polymer. In this structure, 4, 4′-bipyridine-N, N’-dioxide (bpdo) as the linear axle and p-sulfonatocalix[8]arene as the wheel have been reported. The structure provides new opportunities for large calixarenes as wheels to be applied in the field of metal–organic rotaxane frameworks.
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