First metallation of iodo diazines. Iodo and nitrogen directed metallations. Diazines XXII

Add time:08/26/2019    Source:sciencedirect.com

Lithiation of iodopyrazine and 4-iodo-2-methylthiopyrimidine followed by reaction with various electrophiles was successfully achieved and was used to synthesize new pyrazine and pyrimidine derivatives. Iodo and nitrogen directed metallations were observed.

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