Chapter 2 - Phosphonyl Compounds

Add time:08/27/2019    Source:sciencedirect.com

Synthetic methods for phosphonyl compounds are described. The methods cover 37 classes of compounds. These include species of general structure: R(R'O)P(O)H, RP(O)X2 [X = Cl, Br, F, NCO, NCS, OH, OR], RP(O)(X)F [X = OH, Cl, NCO, NCS], ArP(O)(OR)2, (RO)2P(O)C(O)R', (RO)2P(O)CH(OX)R' [X = H, SiMe3], (RO)2P(O)CR2NR2, (RO)2P(O)C=CR2, (RO)2P(O)C≡CR, R(X)P(O)Cl [X = R'O, R'2N, R'S], R(X)P(O)F [X = R'O, R'NH, R'2N, R'S], R(R'O)P(O)X [X = CN, OH], R(X)P(O)OP(O)(X)R [X = F, R'O, R'2N, R'S], RP(O)(NR2)X [X = OR, NR2], RP(O)(X)SR [X = OR, NR2, SR].

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