NOTESPhotochemical Cyclization of N-Butyl-N'-(9-acridinyl)thiourea
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Add time:08/28/2019 Source:sciencedirect.com
The structure elucidation of 2-butylamino-1,3-thiazino-[4,5,6-kl]acridine, isolated after the reaction of 9-isothiocyanato-acridine with butylamine, is described. The same compound was found to be formed by photochemical cyclization of N-butyl-N'-(9-acridinyl)thiourea. The intense fluorescence of this cyclized product serves as the basis for the previously reported analysis of primary amines by reaction with 9-isothiocyanatoacridine.
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