Absolute configuration of a rare Dibenzoylmethane (cas 120-46-7) derivative from Dahlstedtia glaziovii (Fabaceae)
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Add time:08/29/2019 Source:sciencedirect.com
Dibenzoylmethane (cas 120-46-7)s (DBMs) belong to a small group of flavonoids, known as β-hydroxychalcones, rarely found in nature. Despite their biological and chemotaxonomic importance, the absolute configuration of C-8 substituted DBMs has never been reported. Herein, the absolute stereochemistry of 2′-methoxy-8-(α-α-dimethylallyl)-[3′,4′:4″,5″]-furan-dibenzoylmethane is determined using the VCD exciton chirality method, which may be safely applied to other members of this class.
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