Synthesis, characterization, and photo- and electro-luminescence of new Ir(III) complexes with carrier transporting group-functionalized Dibenzoylmethane (cas 120-46-7) ligand for green phosphorescent OLEDs

Add time:09/04/2019    Source:sciencedirect.com

Two new iridium(III) complexes containing the coumarin derivatives as cyclometalated ligands (L) and the carrier transporting group-functionalized Dibenzoylmethane (cas 120-46-7) as ancillary ligands have been successfully synthesized and characterized. The X-ray crystal structure analyses of the free ligands and the complex containing a carbazole-functionalized dibenzoylmethane as ancillary ligand were described. The photophysical properties of the Ir(III) complexes were examined via ultraviolet-visible, photoluminescence spectroscopic spectra. The good thermal stability of the Ir(III) complexes was demonstrated by the thermogravimetric analysis. The doped light-emitting devices using the Ir(III) complexes as dopants were fabricated. The devices based on the complex containing a carbazole-functionalized dibenzoylmethane as ancillary ligand possess better performance as compared with the devices fabricated by the complex containing a 1,3,4-oxadiazole-functionalized dibenzoylmethane as ancillary ligand. The devices based on the former Ir(III) complex with a 15 wt% doping concentration exhibit a maximum efficiency of 13.8 cd/A and a maximum brightness of 4955.7 cd/m2.

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