Surface Science LettersThe adsorption and decomposition of Chromium hexacarbonyl (cas 13007-92-6) on Pd(100)

Add time:09/02/2019    Source:sciencedirect.com

Chromium hexacarbonyl (cas 13007-92-6) [Cr(CO)6] was physisorbed on the Pd(100) surface, and the molecular orientation was determined using reflection-absorption infrared spectroscopy (RAIRS). The thermal decomposition of the compound was observed, by the indirect observation of a modified surface morphology, which caused the adsorption of energetically unfavourable μ1-CO and influenced the growth and structure of subsequently adsorbed Cr(CO)6 layers.

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