Diastereoselective synthesis of the model insect antifeedants related to azadiradione and epoxyazadiradione (cas 18385-59-6) based on intramolecular insertion of α-aryl-α-diazoketones

Add time:08/31/2019    Source:sciencedirect.com

A new practical and stereoselective method for the synthesis of the model insect antifeedant CDE fragment of azadiradione and epoxyazadiradione (cas 18385-59-6), based on intramolecular insertion of α-aryl-α-diazoketones, has been developed. The procedure can be applied to complex systems. A short SAR study is reported.

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