The study of the intramolecular heavy atom effect in 9,10-dichlorophenanthrene and 1,2,3,4-tetrachloronaphthalene (cas 1335-88-2) using PMDR techniques
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Add time:09/03/2019 Source:sciencedirect.com
Using PMDR techniques, the top two zero-field triplet levels in 9,10-dichlorophenanthrene and 1,2,3,4-tetrachloronaphthalene are shown to be most favoured by S1 → T1 ISC and T1 → S0 phosphorescence. Spin—orbit vibronic coupling via CCl out-of-plane modes and static distortions of the heavy atom are responsible for such behaviour respectively.
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