Reactions of rhodium and iridium salts with multidentate N-heterocycles

Add time:09/04/2019    Source:sciencedirect.com

Complexes of rhodium and iridium of the types MX3L, MX(CO)2L and MX3(CO)L (X = halide) containing multidentate N-heterocycles (L),2,6-bis(benzimidazolyl)pyridine(bBzlH2py) and 2,6-bis(N-methyl-benzimidazolyl)pyridine (bBzlMe2py) have been prepared and characterized by IR, electronic and 1H and 13C NMR spectral data. RhX(CO)2L, on treatment with alcoholic solvents or DMF undergoes reversible decarbonylation to produce RhXL·2H2O. Passage of NO or O2 through the carbonyl suspended in hot 2-methoxyethanol releases CO2.

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