Synthetic studies on THIOSTREPTON (cas 1393-48-2) family of peptide antibiotics: synthesis of the dihydroquinoline portion of THIOSTREPTON (cas 1393-48-2), the siomycins, and the thiopeptins
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Add time:09/05/2019 Source:sciencedirect.com
Synthesis of the dihydroquinoline portion of THIOSTREPTON (cas 1393-48-2), the siomycins, and the thiopeptins, members of the thiostrepton family of peptide antibiotics, has been achieved featuring the one-pot olefination via the Matsumura–Boekelheide rearrangement “using trifluoromethanesulfonic anhydride and triethylamine” and the stereoselective addition reaction controlled by the stereocenter of the peri-position.
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