Spectroscopic studies of salts of 4-methylbenzenesulfonic acid III. The spectrum of water in the hexahydrate of copper(II) 4-methylbenzenesulfonate
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Add time:09/08/2019 Source:sciencedirect.com
The appearance of the bands in the O-H and O-D stretching region of the spectra of the title compound and in that of its slightly deuterated analogue indicates a larger spread of the H-bond strengths in the structure of this compound than in that of its cobalt analogue. The numerical values of the OW⋯distances are not appropriate indicators for the hydrogen-bond strengths. The bands due to water librations were located on the basis of their temperature sensitivity and shift on deuteration.
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