Palladium(II)-catalyzed arylation of unactivated C(sp3)-H bonds by using 2,1,3-benzoselenadiazole-4-amine as directing ligand
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Add time:09/02/2019 Source:sciencedirect.com
A modified bidentate directing ligand derived from 2,1,3-benzoselenadiazole (BSeD) was designed and synthesized. It exhibited high regioselectivity in the catalytic activation of unactivated C(sp3)-H bonds with aryl iodides in the presence of palladium catalyst in yields up to 94%.
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