Conductivity, density and adiabatic compressibility of 1-BUTYL-2,3-DIMETHYLIMIDAZOLIUM CHLORIDE (cas 98892-75-2) in aqueous solutions

Add time:07/14/2019    Source:sciencedirect.com

Conductivities, densities and speeds of sound of 1-BUTYL-2,3-DIMETHYLIMIDAZOLIUM CHLORIDE (cas 98892-75-2) in aqueous solutions were measured at 15, 25, and 35 °C. These data have been used to characterize the aggregation process of imidazolium based ionic liquid in the aqueous solution. The critical aggregation concentration (cac) and the degree of ionization, α, were determined by conductivity measurements. Both quantities were used to calculate the standard free energy change of aggregation, ΔGa0. It shows decrease in α and ΔGa0 upon growth of temperature. From density data for the ionic liquid, the apparent molar volume, Vϕ, was calculated. The adiabatic compressibility, βs, changes in adiabatic compressibility upon aggregation, Δβs,agg, and apparent adiabatic compressibilities, βϕ,s, were calculated from measurements of density and ultrasound velocity. Good agreement has been found when comparing with the aggregation properties of 1-butyl-2,3-dimethylimidazolium chloride both from conductivity and molar volume approach.

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