NoteStereospecific synthesis of β-d-allopyranosides by dihydroxylation of β-d-erythro-2,3-dideoxyhex-2-enopyranosides
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Add time:09/03/2019 Source:sciencedirect.com
The synthesis of 4,6-O-benzylidene-β-d-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give β-d-allopyranosides in moderate to excellent yield.
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