Preparation and reactions of methyl(allyl)thallium(III) derivatives

Add time:09/05/2019    Source:sciencedirect.com

Several methyl(allyl)thallium derivatives have been prepared for the first time. The IR and PMR spectra of these compounds indicate the presence of σ-allylthallium bonds. In the cleavage reactions of these compounds with tetramethyltin in methanol or with metal salts such as Hg(OCOCH3)2, PdX2 (X  OCOC2H5 and Cl) and RhCl3·3H2O, preferential cleavage of the allylthallium bond occurs to give propylene in the case of tetramethyltin and allylic derivatives of the metals in the other cases.

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