The crystal structure of (N,N-diethyldithiocarbamato)-bis(2-diphenylphosphinoethyl)phenylphosphineplatinum(II)-tetraphenylborate

Add time:09/03/2019    Source:sciencedirect.com

The structure of [Pt(Et2dtc)(P2P′)]BPh4 (Et2dtcS2CNEt2 and P2P′PhP(CH2CH2PPh2)2) has been determined from three-dimensional X-ray data. Monoclinic crystals of the complex belong to the space group P21/c with cell dimensions a=18.375(2), b=15.724(2), c=20.426(3) Å, β=108.85(1)°, V=5585(3) Å3, Z=4. Residuals are R=0.034 and Rw=0.044 for 4092 observed data. The phosphine ligand is chelated via all three phosphorus atoms while the dithiocarbamate ligand is monodentate, through one sulfur atom, to give a distorted square planar arrangement about the platinum atom. The short non-bonding distance (2.754(3) Å) between the platinum and other sulfur atom indicates there may be some interaction between these two atoms in the solid state.

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