An efficient method for racemization free attachment of 9-fluorenylmethyloxycarbonyl-amino acids to peptide synthesis supports

Add time:09/05/2019    Source:sciencedirect.com

An efficient, general, and racemization free method of covalently attaching N α -Fmoc protected amino acids to solid supports for peptide synthesis is described. The process involves the preparation of 2,4-dichlorophenyl-N α -Fmoc-aminoacyl-4-oxymethyl-phenoxy acetates which can be used to directly and efficiently acylate amine functionalized polymers.

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