Oxidation of toluenes to benzoic acids by oxygen in non-acidic solvents
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Add time:07/15/2019 Source:sciencedirect.com
Oxidation of substituted toluenes by molecular oxygen at one atmosphere to the corresponding substituted benzoic acids in non-acidic solvents was investigated. Satisfactory oxidation of halo-, methoxy-, and cyano-toluenes were achieved using Co(C18H35O2)2/NH4Br or Co(OAc)2/NaBr/AcOH as catalysts in the presence of a radical initiator.
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