Sterically stabilized α-acyl free radicals: α-isoproproxycarbonyl, N-morpholinocarbonyl and cyano bis(pentachlorophenyl)methyl radicals.
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Add time:09/05/2019 Source:sciencedirect.com
The three title radicals, 11a, 11b and 11c have been synthesised by oxidation of the corresponding carbanions with iodine. The radicals are red to purple air stable solids and their ir and esr spectra show considerable interaction between the unpaired electron and the carbonyl or cyano group.
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