Chemical oxidative polymerization of DODECYLBENZENESULFONIC ACID (cas 121-65-3) aniline salt in chloroform

Add time:09/10/2019    Source:sciencedirect.com

Polymerizations of DODECYLBENZENESULFONIC ACID (cas 121-65-3) aniline salt (DBSAn) in chloroform using various electron acceptors were studied as a function of polymer yield and conductivity. Dichlorodicyanobenzoquinone (DDQ) is an effective oxidant for the polymerization of DBSAn to yield sufficient amount of polyaniline. Suspension polymerization of DBSAn in chloroform with a small amount of water containing ammonium persulfate (APS) as an oxidant was found to yield a homogeneous transparent and green-black suspension containing polyaniline. Polyaniline was found to exhibit strong solvatochromism in aqueous and chloroform solutions.

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