Excess molar volumes and viscosity behaviour of binary mixtures of aniline/or N,N-Dimethylaniline (cas 121-69-7) with imidazolium ionic liquids having triflate or bistriflamide anion
-
Add time:09/07/2019 Source:sciencedirect.com
In this study, densities and viscosities of four binary systems {aniline/N,N-Dimethylaniline (cas 121-69-7) + 1-butyl-3-methylimidazolium triflate ([bmim][OTf])} and {aniline/N,N-dimethylaniline + 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][NTf2])} were measured at atmospheric pressure and within the temperature range T = (288.15 to 333.15) K. Excess molar volumes VE, viscosity deviations Δη and excess molar Gibbs energies of activation of viscous flow ∆G∗E were calculated and the results were fitted to a Redlich-Kister polynomial equation. Also, enthalpic and entropic parts of the ∆G∗E function were determined, at the same composition, for three studied systems that exhibit complete miscibility, since {aniline + [bmim][OTf]} is a partially miscible system. Considering the calculated thermodynamic properties, molecular interactions in the investigated binary systems were analysed and are discussed.
We also recommend Trading Suppliers and Manufacturers of N,N-Dimethylaniline (cas 121-69-7). Pls Click Website Link as below: cas 121-69-7 suppliers
Prev:DFT/TD-DFT calculations of the electronic and optical properties of bis-N,N-Dimethylaniline (cas 121-69-7)-based dyes for use in dye-sensitized solar cells
Next:Volumetric and transport properties of binary liquid mixtures of sulfolane with aniline, N,N-Dimethylaniline (cas 121-69-7) and N,N-diethylaniline at different temperatures and atmospheric pressure) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Transformation of N,N-Dimethylaniline (cas 121-69-7)-N-oxides into N-methylindolines by a tandem Polonovski–Mannich reaction09/26/2019
- Synthesis and properties of Fischer carbene complexes of N,N-Dimethylaniline (cas 121-69-7) and anisole π-coordinated to chromium tricarbonyl09/25/2019
- Short CommunicationOne-pot synthesis of N,N-Dimethylaniline (cas 121-69-7)s from nitroarenes with skeletal Cu as chemoselective catalyst09/24/2019
- Determination of thermodynamic properties for protonation equilibrium between isomeric cresols and N,N-Dimethylaniline (cas 121-69-7) in n-hexane medium09/10/2019
- A study of electropolymerization of N,N-Dimethylaniline (cas 121-69-7)09/09/2019
- Volumetric and transport properties of binary liquid mixtures of sulfolane with aniline, N,N-Dimethylaniline (cas 121-69-7) and N,N-diethylaniline at different temperatures and atmospheric pressure09/08/2019
- DFT/TD-DFT calculations of the electronic and optical properties of bis-N,N-Dimethylaniline (cas 121-69-7)-based dyes for use in dye-sensitized solar cells09/06/2019
- Catalytic and stoichiometric oxidation of N,N-Dimethylaniline (cas 121-69-7)s mediated by nonheme oxoiron(IV) complex with tetrapyridyl ligand09/05/2019
- Iron-catalyzed aerobic oxidative cross-coupling amidation of N,N-Dimethylaniline (cas 121-69-7)s09/04/2019