Short communicationImmobilisation of catalytically active proline on H2N-MIL-101(Al) accompanied with reversal in enantioselectivity
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Add time:09/24/2019 Source:sciencedirect.com
Proline-functionalized H2N-MIL-101(Al) was synthesized from l- or d-proline-terephthalic acid and used in the catalytic aldol reaction of p-nitrobenzaldehyde with acetone to achieve up to 95% conversion and an ee-value of 29% but in a reversal in enantioselectivity compared to the reaction under homogeneous l- or d-proline organocatalytic condition.
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