The microwave spectrum and structure of krypton—PHOSPHORUS TRIFLUORIDE (cas 13659-65-9)

Add time:09/08/2019    Source:sciencedirect.com

The rotational spectrum of the weak complex between krypton and phosphorus trifluoride has been observed using a Fourier transform microwave spectrometer with a pulsed supersonic nozzle molecular beam source. The complex is an asymmetric top. The distance rcm between the krypton atom and the center of mass of the PF3 molecule is 4.0722 Å and the angle between the rcm vector and the C3 axis of the PF3 is 68.25°. Based on the centrifugal distortion constant DJ and a pseudodiatomic model, the binding energy of the complex is estimated to be 218 cm−1.

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