Sulphur substituted organotin compounds. Part 9. Crystal and molecular structure and reactions of [(p-chlorophenylthio)methyl]tricyclohexylstannane

Add time:09/06/2019    Source:sciencedirect.com

The crystal and molecular structure of [(p-chlorophenylthio)methyl]tricyclohexylstannane (II) has been determined. In the two independent molecules of monoclinic II there are slightly distorted tetrahedral geometries about tin with intramolecular SnS distances of 3.29(1) and 3.26(1) Å. Compound II reacts with N-bromosuccinimide, I2, Pb(OAc)4 or CF3CO2H to give XCH2SC6H4Cl-p (X = Br, I, AcO or H) and the appropriate tricyclohexyltin species; II is less reactive than Cy3SnCH2SeC6H4Cl-p towards I2. Oxidative cleavage of II by m-ClC6H4CO·O·OH provides mainly CH3S(O)C6H4Cl-p. The absorption maximum for the charge transfer complex of II and (NC)2CC(CN)2 is reported.

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