Synthesis and structure of bismuth copper arsenate, BiCu2AsO6
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Add time:09/10/2019 Source:sciencedirect.com
A new compound with the formula BiCu2AsO6 has been prepared. This dark green compound crystallizes in space group Pnma with a=12.253(1) Å, b=5.280(1) Å, c=7.577(1) Å, and Z=4. The structure contains (BiO2)− chains and (AsO4)3− tetrahedra. Square pyramidal coordination occurs for Cu2+ with the pyramids sharing edges of their bases in pairs to form Cu2O8 dimers. An unusual feature of the Bi3+ coordination is five short bonds to oxygen.
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