The structure and spectroscopic characterization of UO22+ complexes with TETRAETHYL METHYLENEDIPHOSPHONATE (cas 1660-94-2) in solution and in solid state

Add time:09/07/2019    Source:sciencedirect.com

The crystal structure of UO22+ complex with TETRAETHYL METHYLENEDIPHOSPHONATE (cas 1660-94-2), CH2[P(O)(OCH2CH3)2]2, POPO, and its spectroscopic characterization in solution and in solid state are discussed. The complex was also characterized by CHN microanalytical procedures, infrared, absorption and luminescence spectroscopy and by single crystal X-ray diffraction. Uranyl in the [UO2(POPO)(NO3)2] complex is six-coordinated.

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