Reaction of carbonyl compounds with XENON DIFLUORIDE (cas 13709-36-9) in the presence of silicon tetrafluoride
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Add time:09/25/2019 Source:sciencedirect.com
Reaction of various carbonyl compounds with XENON DIFLUORIDE (cas 13709-36-9) in the presence of silicon tetrafluoride was investigated. Aromatic aldehyde, ketones, and α-ketoester react with xenon difluoride to give α,α-difluoroalkyl phenyl ethers. However, acid fluoride, ester, acid cyanide, α-ketocarboxylic acid, or thioester do not afford the corresponding products. In the case of cinnamaldehyde, fluorination was accompanied by intramolecular cyclization to afford fluorinated epoxide.
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