Reactivity of the HoPc2I in the Acetylacetone (cas 123-54-6)–water system
-
Add time:09/28/2019 Source:sciencedirect.com
Reactivity of holmium diphthalocyanine with iodide HoPc2I in the acetylacetone/water system has been investigated. Depending on the water quantity in the system the solvothermal reaction of HoPc2I with acacH/water leads to formation of four different compounds. All these four compounds were obtained in the crystalline form. In equilibrium proportion of HoPc2I to water (molar proportion of 1:1) in excess of acacH the unique complex of [Ho(oPc)(acac)(OAc)]I·0.5(CH3COCH3) – (1) has been obtained. The neutral open phthalocyanine chelate ligand (oPc) is formed from phthalocyaninate ligand in sequence of numerous processes. The oPc chelate ligand shows alternate single and double bonds due to presence of imine bridge (NH). The imine bridge breaks the π-delocalisation within the whole oPc chelate ligand. The sequence of single and double bonds in the oPc ligand has been confirmed by DFT calculations. Increasing of water quantity in the reacting system leads to formation of three different holmium acetates: anhydrous holmium acetate Ho(CH3COO)3 – 2, bis(holmiumacetate) monohydrate [Ho(CH3COO)3]2·H2O – 3 and bis[holmium(diacetate)(triaqua)iodide] monohydrate [Ho(CH3COO)2(H2O)3I]2·H2O – 4. These three holmium acetates differ in the amount of water and have different structures.
We also recommend Trading Suppliers and Manufacturers of Acetylacetone (cas 123-54-6). Pls Click Website Link as below: cas 123-54-6 suppliers
Prev:Comparative solution and structural studies of half-sandwich rhodium and ruthenium complexes bearing curcumin and Acetylacetone (cas 123-54-6)
Next:General CommentaryAn Automated and Qualified Platform Method for Site-Specific Succinimide (cas 123-56-8) and Deamidation Quantitation Using Low-pH Peptide Mapping) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Comparative solution and structural studies of half-sandwich rhodium and ruthenium complexes bearing curcumin and Acetylacetone (cas 123-54-6)10/01/2019
- Fate and implication of Acetylacetone (cas 123-54-6) in photochemical processes for water treatment09/27/2019
- Enhanced decomplexation of Cu(II)-EDTA: The role of Acetylacetone (cas 123-54-6) in Cu-mediated photo-Fenton reactions09/26/2019
- Effects of Acetylacetone (cas 123-54-6) on the photoconversion of pharmaceuticals in natural and pure waters☆09/25/2019
- The Acetylacetone (cas 123-54-6)-water complex in a low-temperature solid argon matrix09/24/2019
- SBA-15:TiO2 nanocomposites: II. Direct and post-synthesis using Acetylacetone (cas 123-54-6)09/10/2019
- Effects of Acetylacetone (cas 123-54-6) on the thermal and photochemical conversion of benzoquinone in aqueous solution09/09/2019
- Comparative study of the photodynamics of malonaldehyde and Acetylacetone (cas 123-54-6)☆09/08/2019