The properties of NMOB/cadmium arachidate alternated multilayers
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Add time:09/29/2019 Source:sciencedirect.com
100 bilayers 2-nitro-5-(N-methyl-N-octadecyl)aminobenzoic acid (NMOB) and cadmium arachidate (CdA) alternated Langmuir–Blodgett (LB) film was fabricated. The thickness of NMOB monolayer is 2.85 nm measured by small angle X-ray diffraction. It shows that NMOB molecule stands vertically in the alternated film. A DFT method, B3LYP, was used to calculate the energies of various conformations of NMOB with 4-31G* basis set. The computational results show that the tilted conformation is the most stable and the energy difference between this conformation and the vertical one is 31 kJ/mol. The refractive indices of NMOB/CdA alternated films were also determined at different wavelengths by waveguide measurement.
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