Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)Diphenyl sulfone (cas 127-63-9) dianhydrides

Add time:09/26/2019    Source:sciencedirect.com

4,4′-Bis(3,4-dicarboxyphenylthio)diphenyl sulfone dianhydride(4,4′-PTPSDA) and 4,4′-bis(2,3-dicarboxyphenylthio)diphenyl sulfone dianhydride(3,3′-PTPSDA) were synthesized from chlorophthalic anhydrides and bis(4-mercaptophenyl)sulfone. Their structures were determined via IR spectra, 1H NMR and elemental analysis. A series of polyimides were prepared from isomeric PTPSDAs and aromatic diamines in 1-methyl-2-pyrrolidinone (NMP) via the conventional two-step method. Polyimides based on 4,4′-PTPSDA and 3,3′-PTPSDA have good solubility in polar aprotic solvents and phenols. The 5% weight-loss temperatures of isomeric polyimides were near 500 °C in N2. DMTA and DSC analyses indicated that the glass-transition temperatures of polyimides from 3,3′-PTPSDA are higher than those of polyimides from 4,4′-PTPSDA. The wide-angle X-ray diffraction showed that all polyimides are amorphous. The polyimides from 3,3′-PTPSDA showed higher permeability but lower permselectivity compared with those from 4,4′-PTPSDA.

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