The synthesis of allylic phosphate derivatives of trans zeatin

Add time:10/01/2019    Source:sciencedirect.com

Phosphitylation of the allylic hydroxy group in 9-tetrahydropyranyltrans-zeatine with salicyl chlorophosphite gives the allyl phosphonate monoester 5, which can be readily converted into the corresponding phosphate 7, methylphosphate 8 or thiophosphate 9. After cleavage of the tetrahydropyranyl group under mild acidic condition allylic phosphate derivatives of trans-zeatin are obtained.

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