A novel synthesis of methyl 5-substituted thiazole-4-carboxylates using 3-bromo-2-isocyanoacrylates (BICA)
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Add time:09/27/2019 Source:sciencedirect.com
A novel synthetic method for methyl 5-substituted thiazole-4-carboxylates (5) by the reaction of methyl 3-substituted 3-bromo-2-isocyanoacrylates(BICA)(1) with hydrogen sulfide in the presence of triethylamine in N,N-dimethylformamide was explored, and the reaction mechanism was elucidated.
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