One-pot three-component synthesis of 3-cyano-4-methyl-2,6-dioxopyridine amino enones

Add time:09/24/2019    Source:sciencedirect.com

(Z)-5-(Arylaminomethylidene)-4-methyl-2,6-dioxo-1,2,5,6-tetrahydropyridine-3-carbonitriles were obtained by three-component condensation of 4-methyl-2,6-dioxo-1,2,5,6-tetrahydropyridine-3-carbonitrile with aromatic amines and trimethyl orthoformate in DMF. According to X-ray data, in the solid phase they exist as amino enone tautomers.

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