Polymer paperMicroenvironments in poly(ethylene terephthalate) film revealed by means of fluorescence measurements

Add time:09/25/2019    Source:sciencedirect.com

The fluorescence behaviour of poly(ethylene terephthalate) (PET) films prepared by using a spin-casting method was measured. The wavelength of the fluorescence peak was found to be dependent on the casting temperature, Tcast. This fluorescence is neither from a ground state dimer nor from an excimer. It is the red-shifted fluorescence of either the phenylene group or the phenylene exciplex due to interactions involving some contributions of charge-transfer stabilization among phenylene and carbonyl groups and/or phenylene groups. Both d.s.c. and i.r. measurements clearly showed that the fluorescence reflects whether the main-chain phenylene ring of PET is in the crystal region or in the amorphous region.

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