Fluorescence and photophysical properties of D-π-A push-pull systems featuring a 4,5-Dicyanoimidazole (cas 1122-28-7) unit
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Add time:09/30/2019 Source:sciencedirect.com
Absorption and fluorescence spectra and fluorescence quantum yields of 18 D-;π-A push-pull compounds were measured. The investigated chromophores consist of 4,5-Dicyanoimidazole (cas 1122-28-7) — bearing donor — substituted and systematically extended π-conjugated spacers. The influence of temperature and solvent polarity on the spectral and photophysical properties was investigated. Employing INDO/S calculations, the structure–property relationships were discussed.
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