CommunicationGlycyrrhizic acid (cas 1405-86-3) based self-assembled helical nanostructures as scaffolds for asymmetric Diels-Alder reaction

Add time:10/01/2019    Source:sciencedirect.com

Glycyrrhizic acid (GA), as a traditional herbal, can self-assemble into helical nanofiber in the water. The formed helical nanostructures can be employed as scaffolds for asymmetric Diels-Alder reaction. Through co-assembling with a series of achiral copper-ligands, the chirality of GA helical nanostructures can be transferred to catalytic site, and resulted assemblies showed moderated enantioselectivity toward catalysis of Diels-Alder reaction.

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