Behavior of 2-(1-cyclohexenyl)cyclohexanone oxime and related oximes under Beckmann rearrangement conditions
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Add time:09/30/2019 Source:sciencedirect.com
The behavior of several alpha-monosubstituted cyclohexanone oximes under Beckmann rearrangement conditions is compared. Alpha-1-chlorocyclohexane and cyclohexane substituted oximes undergo the normal rearrangement, while the alpha-cyclohexene substitution gives rise to fragmentation products. This result is discussed. Synthesis of 6-amino-6(1-cyclohexenyl)hexanoic acid lactam in high yield is described.
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