Coexistence of Differently Capped Trigonal Prismatic C2@Ag7 Cages in a Triple Salt of Silver(I) Acetylide

Add time:09/28/2019    Source:infona.pl

The new silver(I) triple salt 2Ag2C2·AgF·9AgNO3·H2O was prepared by dissolving Ag2C2 in an aqueous solution of AgNO3 and AgBF4. Its crystal structure contains two kinds of monocapped trigonal prismatic C2@Ag7 cages, with the capping atom occurring on one triangular face or one rectangular face.

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