Oxidative Decarboxylation of Arylacetic Acids Mediated by Peroxysulfur Intermediate Generated from 2-Nitrobenzenesulfonyl chloride (cas 1694-92-4) and Superoxide

Add time:09/25/2019    Source:infona.pl

The oxidative decarboxylation of aryl, α,α-diaryl, or arylalkylacetic acids has been achieved by a 2-nitrobenzenesulfonyl peroxy radical intermediate (I) generated by the reaction of 2-Nitrobenzenesulfonyl chloride (cas 1694-92-4) with potassium superoxide at -20°C in dry acetonitrile.

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