Infrared and Raman spectra of 1 2 / 1 3 C-thallium nitroprusside, Tl 2 [Fe(CN) 5 NO]

Add time:09/27/2019    Source:infona.pl

Interferometric infrared and Raman spectra of thallium nitroprusside (Tl 2 [Fe(CN) 5 NO]), with normal isotopic composition or substituted with 1 3 C (98.5%), were obtained from 4000 to 50 cm - 1 at room and low temperature (boiling liquid air). Infrared microscopy used with selected monocrystals allowed the detection of very weak overtone and combination bands. Comparisons are made with other nitroprusside salts, anhydrous and hydrated, and especially with sodium nitroprusside dihydrate.

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