Total Synthesis of New 8‐(Arylmethyl)berbine (cas 131-10-2)s
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Add time:10/01/2019 Source:infona.pl
The total synthesis of the natural compound (8S*,14S*)‐8‐(4′‐hydroxybenzyl)‐2,3‐dimethoxyberbin‐10‐ol and its C‐8 epimer has been conveniently developed by making use of the diastereoselective Stevens rearrangement of the corresponding N‐(arylmethyl)berbinium salts as the key step.
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