Syntheses, crystal structures, and magnetic and luminescent properties of a series of lanthanide coordination polymers with Chelidamic acid (cas 138-60-3) ligand
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Add time:09/30/2019 Source:infona.pl
A series of lanthanide(III) complexes with Chelidamic acid (cas 138-60-3) ligand, [Ln(C 7 H 2 NO 5 )·3H 2 O] n ·nH 2 O (Ln=La (1), Y (2), Sm (3), and Nd (4)), [Gd 2 (C 7 H 2 NO 5 ) 3 ·4H 2 O] n ·2nH 2 O (5) and [Ce(C 7 H 2 NO 5 )·1.5H 2 O] n (6), have been synthesized by hydrothermal method and structurally characterized by single-crystal X-ray diffraction. Complexes 1–4 are isostructural and possess 2D framework. Complex 5 contains two different Gd(III) ions linked through carboxylate group to form a 2D framework. Complex 6 exhibits a (4 4 ) topology 2D network. The variable-temperature magnetic properties of 3 and 5 have been investigated. Furthermore, the photoluminescent properties of 1, 2, 3, and 5 at room temperature were also studied.
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