Thermodynamic Properties of N-(Trimethylsily)Ethyleneimine (cas 151-56-4) N-(Triethylsily)Ethyleneimine (cas 151-56-4) and (Dimethylphenylsilyl)Ethyleneimine (cas 151-56-4) Complexes with Zinc Chloride in the Range 0-340 K

Add time:09/30/2019    Source:infona.pl

Tmperature dependence of heat capacity of N-(trimethylsilyl)ethyleneimine, N-(triethylsilyl)-ethyleneimine, N-(dimethylphenylsilyl)ethyleneimine with zinc chloride was studied in the 5-340 K rangein an adiabatic vacuum calorimeter with ∼0.2% error. From the data obtained tge complexes thermodynamicfunctions C0 p(T), H 0(T)-H 0(0), S 0(T)-S 0(0) and G 0(T)-H 0(0) are obtained in the 0-340 K, as well as fractal dimensions D and characteristic temperatures Θmax for the functions of gractal heat capacity of solid substances.

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